{"id":60,"date":"2024-03-25T07:47:33","date_gmt":"2024-03-25T07:47:33","guid":{"rendered":"https:\/\/www.itim-cj.ro\/PNCDI\/co2omc\/acasa-english\/"},"modified":"2024-03-26T11:23:51","modified_gmt":"2024-03-26T11:23:51","slug":"acasa-english","status":"publish","type":"page","link":"https:\/\/www.itim-cj.ro\/PNCDI\/co2omc\/","title":{"rendered":"Home"},"content":{"rendered":"<p>[et_pb_section fb_built=&#8221;1&#8243; admin_label=&#8221;Hero&#8221; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; background_color=&#8221;#ffffff&#8221; custom_padding=&#8221;0px|||||&#8221; bottom_divider_color=&#8221;#ededed&#8221; bottom_divider_height=&#8221;40%&#8221; bottom_divider_height_tablet=&#8221;&#8221; bottom_divider_height_phone=&#8221;&#8221; bottom_divider_height_last_edited=&#8221;on|phone&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_row column_structure=&#8221;1_4,3_4&#8243; use_custom_gutter=&#8221;on&#8221; gutter_width=&#8221;2&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; width=&#8221;100%&#8221; custom_margin=&#8221;||||false|false&#8221; custom_padding=&#8221;||||false|false&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;1_4&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;|||&#8221; global_colors_info=&#8221;{}&#8221; custom_padding__hover=&#8221;|||&#8221;][et_pb_image src=&#8221;https:\/\/www.itim-cj.ro\/PNCDI\/co2omc\/wp-content\/uploads\/2024\/03\/Sigla-INCDTIM-100.jpg&#8221; title_text=&#8221;Sigla INCDTIM 100&#8243; url=&#8221;http:\/\/ro.itim-cj.ro&#8221; url_new_window=&#8221;on&#8221; align=&#8221;right&#8221; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; width=&#8221;25%&#8221; max_width=&#8221;50px&#8221; global_colors_info=&#8221;{}&#8221;][\/et_pb_image][\/et_pb_column][et_pb_column type=&#8221;3_4&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;|||&#8221; global_colors_info=&#8221;{}&#8221; custom_padding__hover=&#8221;|||&#8221;][et_pb_text _builder_version=&#8221;4.24.2&#8243; _module_preset=&#8221;default&#8221; text_font=&#8221;Montserrat|300|||||||&#8221; text_text_color=&#8221;#353535&#8243; text_font_size=&#8221;18px&#8221; text_line_height=&#8221;2.3em&#8221; header_font=&#8221;||||||||&#8221; header_font_size=&#8221;40px&#8221; header_line_height=&#8221;1.4em&#8221; header_4_line_height=&#8221;1.4em&#8221; custom_margin=&#8221;8px||30px||false|false&#8221; custom_margin_last_edited=&#8221;off|desktop&#8221; custom_padding=&#8221;|0px||||&#8221; header_font_size_tablet=&#8221;30px&#8221; header_font_size_phone=&#8221;24px&#8221; header_font_size_last_edited=&#8221;on|desktop&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<p><strong><em>National Institute for Research and Development <\/em><\/strong><strong><em>of <br \/>Isotopic and Molecular Technologies &#8211; INCDTIM<\/em><\/strong><\/p>\n<p>[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row column_structure=&#8221;1_2,1_2&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; custom_margin=&#8221;-28px|auto||auto||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;1_2&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;|||&#8221; global_colors_info=&#8221;{}&#8221; custom_padding__hover=&#8221;|||&#8221;][et_pb_image src=&#8221;https:\/\/www.itim-cj.ro\/PNCDI\/co2omc\/wp-content\/uploads\/2024\/03\/logo.png&#8221; title_text=&#8221;logo&#8221; show_bottom_space=&#8221;off&#8221; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; width=&#8221;30%&#8221; global_colors_info=&#8221;{}&#8221;][\/et_pb_image][et_pb_text _builder_version=&#8221;4.24.2&#8243; _module_preset=&#8221;default&#8221; text_font=&#8221;Montserrat|300|||||||&#8221; text_text_color=&#8221;#353535&#8243; text_font_size=&#8221;18px&#8221; text_line_height=&#8221;2.5em&#8221; header_font=&#8221;|600|||||||&#8221; header_text_color=&#8221;#2b3242&#8243; header_font_size=&#8221;34px&#8221; header_line_height=&#8221;1.7em&#8221; header_2_font=&#8221;|600|||||||&#8221; header_2_font_size=&#8221;29px&#8221; header_2_line_height=&#8221;1.5em&#8221; max_width=&#8221;600px&#8221; custom_margin=&#8221;|-35px|30px|||&#8221; custom_margin_last_edited=&#8221;off|desktop&#8221; header_font_size_tablet=&#8221;30px&#8221; header_font_size_phone=&#8221;24px&#8221; header_font_size_last_edited=&#8221;on|desktop&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h1><strong>CO<sub>2<\/sub> methanation by MOF based \/ derived ordered mesoporous catalysts<\/strong><\/h1>\n<p>[\/et_pb_text][\/et_pb_column][et_pb_column type=&#8221;1_2&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;|||&#8221; global_colors_info=&#8221;{}&#8221; custom_padding__hover=&#8221;|||&#8221;][et_pb_image src=&#8221;https:\/\/www.itim-cj.ro\/PNCDI\/co2omc\/wp-content\/uploads\/2024\/03\/Site-TE.jpg&#8221; title_text=&#8221;Site TE&#8221; align_tablet=&#8221;center&#8221; align_phone=&#8221;&#8221; align_last_edited=&#8221;on|desktop&#8221; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; width=&#8221;100%&#8221; custom_margin=&#8221;50px|||49px|false|false&#8221; animation_style=&#8221;zoom&#8221; animation_direction=&#8221;bottom&#8221; animation_intensity_zoom=&#8221;4%&#8221; global_colors_info=&#8221;{}&#8221;][\/et_pb_image][\/et_pb_column][\/et_pb_row][\/et_pb_section][et_pb_section fb_built=&#8221;1&#8243; admin_label=&#8221;About Us&#8221; module_id=&#8221;contact&#8221; _builder_version=&#8221;4.24.2&#8243; _module_preset=&#8221;default&#8221; background_color=&#8221;#e27705&#8243; custom_margin=&#8221;||||false|false&#8221; custom_padding=&#8221;50px||50px||false|false&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_row column_structure=&#8221;1_2,1_2&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; custom_margin=&#8221;|||&#8221; custom_padding=&#8221;20px|0px|25px|0px|false|false&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;1_2&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;|||&#8221; global_colors_info=&#8221;{}&#8221; custom_padding__hover=&#8221;|||&#8221;][et_pb_text _builder_version=&#8221;4.24.2&#8243; _module_preset=&#8221;default&#8221; text_font=&#8221;Montserrat|300|||||||&#8221; text_text_color=&#8221;#ffffff&#8221; text_font_size=&#8221;17px&#8221; header_font=&#8221;||||||||&#8221; header_2_font=&#8221;||||||||&#8221; header_3_font=&#8221;||||||||&#8221; header_3_font_size=&#8221;24px&#8221; header_3_line_height=&#8221;1.4em&#8221; background_layout=&#8221;dark&#8221; width=&#8221;100%&#8221; header_2_font_size_tablet=&#8221;30px&#8221; header_2_font_size_phone=&#8221;24px&#8221; header_2_font_size_last_edited=&#8221;off|desktop&#8221; header_3_font_size_tablet=&#8221;30px&#8221; header_3_font_size_phone=&#8221;24px&#8221; header_3_font_size_last_edited=&#8221;off|desktop&#8221; locked=&#8221;off&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h3>Project financed by <span style=\"color: #c5458e;\"><a href=\"https:\/\/uefiscdi.gov.ro\/\" target=\"_blank\" rel=\"noopener noreferrer\" style=\"color: #ebf10;\">UEFISCDI<\/a><\/span><\/h3>\n<p><strong>Project Code:<\/strong> TE \u2013 PN-III-P1-1.1-TE-2019-1447<\/p>\n<p><strong>Program:\u00a0<\/strong>PNCDI III, Programul 1 \u2013 Dezvoltarea sistemului na\u021bional de CD \/ Resurse Umane<\/p>\n<p><strong>Project Type:\u00a0<\/strong>Proiecte de cercetare pentru stimularea tinerelor echipe independente (TE)<\/p>\n<p><strong>Contract Nr.<\/strong>: TE 161 \/ 2020<\/p>\n<p><strong>Duration: <\/strong>01.11.2020 &#8211; 31.10.2022<\/p>\n<p>[\/et_pb_text][\/et_pb_column][et_pb_column type=&#8221;1_2&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;|||&#8221; global_colors_info=&#8221;{}&#8221; custom_padding__hover=&#8221;|||&#8221;][et_pb_text _builder_version=&#8221;4.24.2&#8243; _module_preset=&#8221;default&#8221; text_font=&#8221;Montserrat|300|||||||&#8221; header_font=&#8221;||||||||&#8221; header_2_font=&#8221;||||||||&#8221; header_3_font=&#8221;||||||||&#8221; header_3_font_size=&#8221;24px&#8221; header_3_line_height=&#8221;1.4em&#8221; header_4_font=&#8221;||||||||&#8221; header_4_line_height=&#8221;1.4em&#8221; background_layout=&#8221;dark&#8221; header_2_font_size_tablet=&#8221;30px&#8221; header_2_font_size_phone=&#8221;24px&#8221; header_2_font_size_last_edited=&#8221;off|desktop&#8221; header_3_font_size_tablet=&#8221;30px&#8221; header_3_font_size_phone=&#8221;24px&#8221; header_3_font_size_last_edited=&#8221;off|desktop&#8221; locked=&#8221;off&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h3>Project leader:<\/h3>\n<h4><strong>Dr. Maria MIHE\u021a<br \/> <\/strong><\/h4>\n<h4>e-mail: maria.mihet[at]itim-cj[dot]ro<\/h4>\n<h4>Phone: (+40)264-584037, ext. 122,129<\/h4>\n<h4>fax: (+40)264-420042<\/h4>\n<p><strong><em>INCDTIM &#8211; National Institute for Research and Development <\/em><\/strong><strong><em>of Isotopic and Molecular Technologies, <\/em><\/strong><strong><em>Department of Mass Spectrometry, Chromatography and Applied Physics<\/em><\/strong><\/p>\n<h4><strong>67-103 Donat Str., PO Box 700,\u00a0RO-400293, Cluj-Napoca, Romania<\/strong><\/h4>\n<p>[\/et_pb_text][\/et_pb_column][\/et_pb_row][\/et_pb_section][et_pb_section fb_built=&#8221;1&#8243; admin_label=&#8221;About Us&#8221; module_id=&#8221;abstract&#8221; _builder_version=&#8221;4.24.2&#8243; _module_preset=&#8221;default&#8221; background_enable_color=&#8221;off&#8221; custom_margin=&#8221;||||false|false&#8221; custom_padding=&#8221;50px||50px||false|false&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_row _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;4_4&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;|||&#8221; global_colors_info=&#8221;{}&#8221; custom_padding__hover=&#8221;|||&#8221;][et_pb_divider color=&#8221;#0c71c3&#8243; divider_weight=&#8221;3px&#8221; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; max_width=&#8221;100px&#8221; module_alignment=&#8221;center&#8221; custom_margin=&#8221;||0px|&#8221; locked=&#8221;off&#8221; global_colors_info=&#8221;{}&#8221;][\/et_pb_divider][et_pb_text _builder_version=&#8221;4.24.2&#8243; _module_preset=&#8221;default&#8221; text_font=&#8221;Montserrat|300|||||||&#8221; text_text_color=&#8221;#0c71c3&#8243; text_line_height=&#8221;2em&#8221; header_font=&#8221;||||||||&#8221; header_2_font=&#8221;||||||||&#8221; header_2_font_size=&#8221;36px&#8221; header_2_line_height=&#8221;1.4em&#8221; text_orientation=&#8221;center&#8221; max_width=&#8221;700px&#8221; module_alignment=&#8221;center&#8221; custom_margin=&#8221;|||&#8221; custom_margin_last_edited=&#8221;off|desktop&#8221; header_2_font_size_tablet=&#8221;30px&#8221; header_2_font_size_phone=&#8221;24px&#8221; header_2_font_size_last_edited=&#8221;on|phone&#8221; locked=&#8221;off&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h2><span style=\"color: #333399;\">Abstract<\/span><\/h2>\n<p>[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row use_custom_gutter=&#8221;on&#8221; gutter_width=&#8221;2&#8243; padding_top_bottom_link_1=&#8221;false&#8221; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; background_color=&#8221;#003bde&#8221; use_background_color_gradient=&#8221;on&#8221; background_color_gradient_direction=&#8221;160deg&#8221; background_color_gradient_stops=&#8221;#ffffff 0%|#ffffff 100%&#8221; background_color_gradient_start=&#8221;#ffffff&#8221; background_color_gradient_end=&#8221;#ffffff&#8221; width=&#8221;100%&#8221; module_alignment=&#8221;center&#8221; custom_margin=&#8221;||20px||false|false&#8221; custom_padding=&#8221;|||&#8221; border_style_all=&#8221;none&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;4_4&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;|||&#8221; global_colors_info=&#8221;{}&#8221; custom_padding__hover=&#8221;|||&#8221;][et_pb_text _builder_version=&#8221;4.24.2&#8243; _module_preset=&#8221;default&#8221; text_font=&#8221;|300|||||||&#8221; text_font_size=&#8221;18px&#8221; text_orientation=&#8221;center&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<p>Methanation of CO<sub>2<\/sub> is receiving a revived scientific and technological interest: chemical storage of renewable energy as CH<sub>4<\/sub> (Power-to-Gas concept), combined with the use of CO<sub>2<\/sub> (CO<sub>2<\/sub> capture and utilization) bring both an energetic and an environmental advantage. Highly efficient CO<sub>2<\/sub> methanation catalysts, with good CH<sub>4<\/sub> selectivity should have catalytic functionalities ensuring both CO<sub>2<\/sub> and H<sub>2<\/sub> activation. In this context, metal-organic frameworks (MOFs), \u2013 a class of extended coordination networks obtained by assembling metal centers to organic linkers \u2013 could ensure enhanced dispersion of active metals inside their ordered porous structure, while their gas sorption and storage capacity could be beneficial in respect to CO<sub>2<\/sub> activation.<\/p>\n<p>The main objective of the project is the development of ordered mesoporous MOF-based and MOF-derived Ni catalysts with enhanced catalytic and operational performance in the methanation of CO<sub>2<\/sub>. Two strategies are pursued: (a) nucleation of MOF crystals on preshaped solid macrostructures (MOF-based catalysts), and (b) sacrificial use by thermolysis of MOFs to form MOF-derived structures, which inherit the characteristics and properties of the original MOF (high surface area, ordered porous structure, uniform distribution of constituent elements). Thus, after Ni nanoparticle incorporation, ordered mesoporous catalysts could be obtained, with enhanced mass transfer (better accessibility of active sites) and heat integration (better conductive heat transfer) in the catalytic bed. MOF-based and MOF-derived ordered mesoporous Ni catalysts will be structurally, morphologically and functionally characterized, while catalytic tests will pursue the evaluation of catalytic performance under differential and integral conditions, at different temperatures, CO<sub>2<\/sub>:H<sub>2<\/sub> ratios, or flow conditions. Stability tests will allow the evaluation of the catalysts life time, while deactivation possibilities might be investigated and regeneration methods proposed.<\/p>\n<p>[\/et_pb_text][\/et_pb_column][\/et_pb_row][\/et_pb_section][et_pb_section fb_built=&#8221;1&#8243; admin_label=&#8221;About Us&#8221; module_id=&#8221;objectives&#8221; _builder_version=&#8221;4.24.2&#8243; _module_preset=&#8221;default&#8221; background_color=&#8221;#e27705&#8243; custom_margin=&#8221;||||false|false&#8221; custom_padding=&#8221;52px||50px||false|false&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_row padding_top_bottom_link_1=&#8221;false&#8221; module_id=&#8221;#objectives&#8221; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; background_enable_color=&#8221;off&#8221; background_color_gradient_direction=&#8221;160deg&#8221; background_enable_image=&#8221;off&#8221; background_size=&#8221;initial&#8221; width=&#8221;100%&#8221; max_width=&#8221;1382px&#8221; module_alignment=&#8221;center&#8221; custom_margin=&#8221;|auto|-3px|auto|false|false&#8221; custom_padding=&#8221;|||&#8221; border_radii=&#8221;on|10px|10px|10px|10px&#8221; border_style_all=&#8221;none&#8221; border_width_bottom=&#8221;14px&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;4_4&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;|||&#8221; global_colors_info=&#8221;{}&#8221; custom_padding__hover=&#8221;|||&#8221;][et_pb_text _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; text_font=&#8221;Montserrat|300|||||||&#8221; text_text_color=&#8221;#8300e9&#8243; text_line_height=&#8221;2em&#8221; header_font=&#8221;||||||||&#8221; header_text_color=&#8221;#ffffff&#8221; header_2_font=&#8221;||||||||&#8221; header_2_font_size=&#8221;36px&#8221; header_2_line_height=&#8221;1.4em&#8221; background_color=&#8221;rgba(0,0,0,0)&#8221; text_orientation=&#8221;center&#8221; max_width=&#8221;700px&#8221; module_alignment=&#8221;center&#8221; custom_margin=&#8221;|||&#8221; custom_margin_last_edited=&#8221;off|desktop&#8221; header_2_font_size_tablet=&#8221;30px&#8221; header_2_font_size_phone=&#8221;24px&#8221; header_2_font_size_last_edited=&#8221;on|phone&#8221; locked=&#8221;off&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h2><span style=\"color: #ffffff;\">Objectives<\/span><\/h2>\n<p>[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row column_structure=&#8221;1_2,1_2&#8243; padding_top_bottom_link_1=&#8221;false&#8221; module_id=&#8221;#objectives&#8221; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; background_enable_color=&#8221;off&#8221; background_color_gradient_direction=&#8221;160deg&#8221; background_enable_image=&#8221;off&#8221; background_size=&#8221;initial&#8221; width=&#8221;100%&#8221; max_width=&#8221;1382px&#8221; module_alignment=&#8221;center&#8221; custom_margin=&#8221;|auto|-3px|auto|false|false&#8221; custom_padding=&#8221;|||&#8221; border_radii=&#8221;on|10px|10px|10px|10px&#8221; border_style_all=&#8221;none&#8221; border_width_bottom=&#8221;14px&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;1_2&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;|||&#8221; global_colors_info=&#8221;{}&#8221; custom_padding__hover=&#8221;|||&#8221;][et_pb_text _builder_version=&#8221;4.24.2&#8243; _module_preset=&#8221;default&#8221; text_font=&#8221;|300|||||||&#8221; text_font_size=&#8221;20px&#8221; text_orientation=&#8221;center&#8221; background_layout=&#8221;dark&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<p>The <strong>main objective<\/strong> of the present project proposal is the development of ordered mesoporous MOF-based and MOF-derived Ni catalysts with enhanced catalytic and operational performance in the CO<sub>2<\/sub> methanation process.<\/p>\n<p>From the catalytic performance point of view, high CO<sub>2<\/sub> conversion with corresponding excellent methane selectivity are aimed, with good stability and minimal deactivation.<\/p>\n<p>\u00a0The <strong><em>specific objectives<\/em><\/strong> derived from this main objective are:<\/p>\n<p><strong>O1 \u2013 <\/strong>Synthesis and characterization of MOF-based ordered mesoporous Ni catalysts.<\/p>\n<p><strong>O2<\/strong> <strong>\u2013<\/strong> Synthesis and characterization of MOF-derived ordered mesoporous Ni catalysts.<\/p>\n<p><strong>O3<\/strong> <strong>\u2013<\/strong> Catalytic activity performance of MOF-based and MOF-derived ordered mesoporous Ni catalysts \u2013 comparative study in the CO<sub>2<\/sub> methanation reaction (experimental set-up, catalytic tests under differential and integral reaction conditions, stability tests, deactivation tests).<\/p>\n<p>[\/et_pb_text][\/et_pb_column][et_pb_column type=&#8221;1_2&#8243; 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